《CuxS counter electrodes in-situ prepared via the sulfidation of magnetron sputtering Cu film for quantum dot sensitized solar cells》

  • 来源专题:广州能源研究所信息监测
  • 编译者: giecinfo
  • 发布时间:2016-04-14
  • The nanosheet-structured CuxS thin films used as counter electrodes (CEs) for CdS/CdSe quantum dot sensitized solar cells (QDSSCs) have been in situ prepared via the sulfidation of Cu nanoparticles deposited on F-doped SnO2 glass (FTO glass) substrate by magnetron sputtering method. The thickness of the deposited Cu film affects the morphology and thickness of the obtained CuxS films. The CuxS nanosheet films have good adhesion with FTO glass and the surface exhibits uniform morphology. The characteristics of QDSSCs are studied in more detail by photocurrent-voltage performance measurements, incident photon-to-current conversion efficiency (IPCE) and electrochemical impedance spectroscopy (EIS). The CuxS on FTO glass (CuxS/FTO) CEs show much higher power conversion efficiency (PCE) and IPCE than those of the Pt on FTO (Pt/FTO) CE because of their superior carrier mobility and electro-catalytic ability for the polysulfide redox reactions. Based on an optimal CuxS film thickness of 2.7 μm obtained by the sulfidation of the Cu film thickness of 300 nm on FTO, the best photovoltaic performance with PCE of 3.67% (Jsc = 16.47 mA cm−2, Voc = 0.481 V, FF = 0.46) under full one-sun illumination is achieved.

相关报告
  • 《Wearable Solar Cells by Stacking Textile Electrodes?》

    • 来源专题:绿色印刷—可穿戴电子
    • 编译者:张宗鹏
    • 发布时间:2016-04-13
    • Abstract A new and general method to produce flexible, wearable dye-sensitized solar cell (DSC) textiles by the stacking of two textile electrodes has been developed. A metal–textile electrode that was made from micrometer-sized metal wires was used as a working electrode, while the textile counter electrode was woven from highly aligned carbon nanotube fibers with high mechanical strengths and electrical conductivities. The resulting DSC textile exhibited a high energy conversion efficiency that was well maintained under bending. Compared with the woven DSC textiles that are based on wire-shaped devices, this stacked DSC textile unexpectedly exhibited a unique deformation from a rectangle to a parallelogram, which is highly desired in portable electronics. This lightweight and wearable stacked DSC textile is superior to conventional planar DSCs because the energy conversion efficiency of the stacked DSC textile was independent of the angle of incident light.
  • 《Aqueous Metal Oxide Inks for Modifying Electrode Work Function in Polymer Solar Cells》

    • 来源专题:绿色印刷—LED
    • 编译者:张宗鹏
    • 发布时间:2016-04-13
    • A method to prepare aqueous metal oxide inks for tuning the work function (WF) of electrodes is demonstrated. Thin films prepared from the metal oxide ink based on vanadium oxide (V2O5) nanoparticles are found to increase the WF of an indium-tin-oxide (ITO) electrode. ITO substrates modified with V2O5 films are applied as a hole selective layer (HSL) in polymer solar cells (PSCs) using a poly(3-hexylthiophene) and [6,6]-phenyl-C61 butyric acid methyl ester blend as a photoactive layer. The PSCs prepared with V2O5-modified ITO show better device performance, achieving a power conversion efficiency of 3.6%, demonstrating 15% enhancement compared to conventional ITO/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT-PSS) based devices. Furthermore, ITO/V2O5-modified devices exhibit better ambient stability with 60% improvement in device lifetime than those using PEDOT:PSS as an HSL. This solution-processable and highly stable WF-modifying metal oxide film can be a potential alternative material for engineering interfaces in optoelectronic devices.