《Dye-sensitized solar cells based on anatase- and brookite-TiO2: enhancing performance through optimization of phase composition, morphology and device architecture》

  • 来源专题:现代化工
  • 编译者: 武春亮
  • 发布时间:2024-06-26




















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    Dye-sensitized solar cells based on anatase- and brookite-TiO2: enhancing performance through optimization of phase composition, morphology and device architecture


    Mobina Khazaei1, Mohammad Reza Mohammadi2 and Yuning Li2




    Accepted Manuscript online 21 June 2024
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    DOI 10.1088/1361-6528/ad5aa1

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    Author e-mailsmrm@uwaterloo.ca
    Author affiliations1
    Sharif University of Technology, Azadi Ave., Tehran, Tehran, NA, Iran (the Islamic Republic of)
    2
    University of Waterloo, 200 University Ave W, Waterloo, Ontario, N2L 3G1, CANADA

    ORCID iDsMohammad Reza Mohammadi https://orcid.org/0000-0001-7999-3233Yuning Li https://orcid.org/0000-0003-3679-8133


    Dates

    Received 21 April 2024
    Revised 8 June 2024
    Accepted 21 June 2024
    Accepted Manuscript online 21 June 2024







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    10.1088/1361-6528/ad5aa1

    Abstract



    Herein, we demonstrate an optimization of dye-sensitized solar cells (DSSCs) through the development of single-layer and double-layer configurations. Focusing on the incorporation of brookite and anatase phases in varying ratios, the study aims to determine the optimal composition for enhanced photovoltaic performance. The active layer, composed of anatase- and brookite-TiO2 nanoparticles, is further modified with a scattering layer comprising a mixture of anatase nanoparticles and brookite-TiO2 in the form nanocube or rice-like particles. The synthesis of TiO2 nanostructures with various morphologies and phase compositions and their subsequent application in single-layer and double layer DSSCs are presented. The results highlight the superior light-harvesting capabilities achieved through the strategic incorporation of brookite phase into the anatase phase, emphasizing the importance of optimizing the anatase: brookite ratio. The single-layer DSSCs exhibit a peak efficiency of 8.73%, achieved with a composition of 30 wt.% brookite and 70 wt.% anatase at a thickness of 15 microns. In the context of double-layer DSSCs, the combined optimization of the active layer composition, scattering layer morphology, and utilization of anatase nanoparticles leads to a remarkable efficiency of 9.18%. These findings underscore the critical role of composition and morphology in enhancing the performance of DSSCs, showcasing the potential for brookite-based DSSCs in solar energy conversion.




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  • 原文来源:https://iopscience.iop.org/article/10.1088/1361-6528/ad5aa1/meta
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