《Modulation of mechanical resonance by chemical potential oscillation in graphene》

  • 来源专题:绿色印刷—LED
  • 编译者: 张宗鹏
  • 发布时间:2016-04-13
  • The classical picture of the force on a capacitor assumes a large density of electronic states, such that the electrochemical potential of charges added to the capacitor is given by the external electrostatic potential and the capacitance is determined purely by geometry1. Here we consider capacitively driven motion of a nano-mechanical resonator with a low density of states, in which these assumptions can break down2, 3, 4, 5. We find three leading-order corrections to the classical picture: the first of which is a modulation in the static force due to variation in the internal chemical potential; the second and third are changes in the static force and dynamic spring constant due to the rate of change of chemical potential, expressed as the quantum (density of states) capacitance6, 7. As a demonstration, we study capacitively driven graphene mechanical resonators, where the chemical potential is modulated independently of the gate voltage using an applied magnetic field to manipulate the energy of electrons residing in discrete Landau levels8, 9, 10. In these devices, we observe large periodic frequency shifts consistent with the three corrections to the classical picture. In devices with extremely low strain and disorder, the first correction term dominates and the resonant frequency closely follows the chemical potential. The theoretical model fits the data with only one adjustable parameter representing disorder-broadening of the Landau levels. The underlying electromechanical coupling mechanism is not limited by the particular choice of material, geometry, or mechanism for variation in the chemical potential, and can thus be extended to other low-dimensional systems.

  • 原文来源:;http://www.nature.com/nphys/journal/v12/n3/full/nphys3576.html
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  • 《Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage》

    • 来源专题:绿色印刷—可穿戴电子
    • 编译者:张宗鹏
    • 发布时间:2016-04-13
    • Structured Abstract Background The integration of graphene in photovoltaic modules, fuel cells, batteries, supercapacitors, and devices for hydrogen generation offers opportunities to tackle challenges driven by the increasing global energy demand. Graphene’s two-dimensional (2D) nature leads to a theoretical surface-to-mass ratio of ~2600 m2/g, which combined with its high electrical conductivity and flexibility, gives it the potential to store electric charge, ions, or hydrogen. Other 2D crystals, such as transition metal chalcogenides (TMDs) and transition metal oxides, are also promising and are now gaining increasing attention for energy applications. The advantage of using such 2D crystals is linked to the possibility of creating and designing layered artificial structures with “on-demand” properties by means of spin-on processes, or layer-by-layer assembly. This approach exploits the availability of materials with metallic, semiconducting, and insulating properties. Advances The success of graphene and related materials (GRMs) for energy applications crucially depends on the development and optimization of production methods. High-volume liquid-phase exfoliation is being developed for a wide variety of layered materials. This technique is being optimized to control the flake size and to increase the edge-to-surface ratio, which is crucial for optimizing electrode performance in fuel cells and batteries. Micro- or nanocrystal or flake edge control can also be achieved through chemical synthesis. This is an ideal route for functionalization, in order to improve storage capacity. Large-area growth via chemical vapor deposition (CVD) has been demonstrated, producing material with high structural and electronic quality for the preparation of transparent conducting electrodes for displays and touch-screens, and is being evaluated for photovoltaic applications. CVD growth of other multicomponent layered materials is less mature and needs further development. Although many transfer techniques have been developed successfully, further improvement of high-volume manufacturing and transfer processes for multilayered heterostructures is needed. In this context, layer-by-layer assembly may enable the realization of devices with on-demand properties for targeted applications, such as photovoltaic devices in which photon absorption in TMDs is combined with charge transport in graphene. Outlook Substantial progress has been made on the preparation of GRMs at the laboratory level. However, cost-effective production of GRMs on an industrial scale is needed to create the future energy value chain. Applications that could benefit the most from GRMs include flexible electronics, batteries with efficient anodes and cathodes, supercapacitors with high energy density, and solar cells. The realization of GRMs with specific transport and insulating properties on demand is an important goal. Additional energy applications of GRMs comprise water splitting and hydrogen production. As an example, the edges of MoS2 single layers can oxidize fuels—such as hydrogen, methanol, and ethanol—in fuel cells, and GRM membranes can be used in fuel cells to improve proton exchange. Functionalized graphene can be exploited for water splitting and hydrogen production. Flexible and wearable devices and membranes incorporating GRMs can also generate electricity from motion, as well as from water and gas flows.
  • 《Improved-quality graphene films via the synergism of large nanosheet aligning and nanotube bridging for flexible supercapacitors》

    • 来源专题:现代化工
    • 编译者:武春亮
    • 发布时间:2024-07-28
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(2014 - 2018)Waves Random Media (1991 - 2004) Volume number: Issue number (if known): Article or page number: Nanotechnology Purpose-led Publishing is a coalition of three not-for-profit publishers in the field of physical sciences: AIP Publishing, the American Physical Society and IOP Publishing. Together, as publishers that will always put purpose above profit, we have defined a set of industry standards that underpin high-quality, ethical scholarly communications. We are proudly declaring that science is our only shareholder. ACCEPTED MANUSCRIPT Improved-quality graphene films via the synergism of large nanosheet aligning and nanotube bridging for flexible supercapacitors Xuan Xu1, Zhenhu Li1, Haoxiang Li2, Yongsu Li1, Yu Zeng1 and Shuangyi Liu1 Accepted Manuscript online 25 July 2024 ? © 2024 IOP Publishing Ltd What is an Accepted Manuscript? DOI 10.1088/1361-6528/ad6774 Download Accepted Manuscript PDF Figures Skip to each figure in the article Tables Skip to each table in the article References Citations Article data Skip to each data item in the article What is article data? Open science Article metrics Submit Submit to this Journal Permissions Get permission to re-use this article Share this article Article and author information Author e-mailslizhenhu@cigit.ac.cn Author affiliations1 Chinese Academy of Sciences Chongqing Institute of Green and Intelligent Technology, Chongqing 400714, P.R. China, Chongqing, Sichuan, 400714, CHINA 2 Chinese Academy of Sciences Chongqing Institute of Green and Intelligent Technology, Chongqing 400714, P.R. China, Chongqing, Sichuan, 401122, CHINA ORCID iDsZhenhu Li https://orcid.org/0000-0001-8574-783X Dates Received 17 January 2024 Revised 22 April 2024 Accepted 25 July 2024 Accepted Manuscript online 25 July 2024 Peer review information Method: Single-anonymous Revisions: 1 Screened for originality? Yes Journal RSS Sign up for new issue notifications 10.1088/1361-6528/ad6774 Abstract Scalable production of reduced graphene oxide (rGO) films with high mechanical-electrical properties are desirable candidates for wearable electronics devices and energy storage applications. Removing structural incompleteness such as wrinkles or voids in the graphene films generated from the assemble process would greatly optimize their mechanical properties. However, the densely stacked graphene sheets in the films degrades their ionic kinetics and thus limits their development. Here, a horizontal-longitudinal-structure modulating strategy is demonstrated to produce enhanced mechanical, conductive and capacitive graphene films. Typically, two-dimensional (2D) large graphene sheets (LGS) induce regular stacking of GO during assembling process to reduce wrinkles, while one-dimensional (1D) single-walled carbon nanotubes (SWCNT) bridge with graphene sheets to strengthen the multidirectional intercalation and reduce GO layer restacking. The simultaneous incorporation of LGS and SWCNT synergistically makes fine microstructure with improving the alignment of graphene sheets, increasing continuous conductive pathways to facilitate electron transport, and enlarging interlayer spacing to promote the electrolyte ion diffusion. As a result, the obtained graphene films are flat and exhibit signally reinforced mechanical properties, electrical conductivity (38727 S m-1), as well as specific capacitance (232 F g-1) as supercapacitor electrodes than those of original rGO films. Moreover, owing to the comprehensive improved properties, the flexible gel supercapacitor assembled by the graphene film-based electrodes shows high energy density, good flexibility and excellent cycling stability (93.8% capacitance retention after 10000 cycles). This work provides a general strategy to manufacture robust graphene structural materials for energy storage applications in flexible and wearable electronics. Export citation and abstract BibTeX RIS During the embargo period (the 12 month period from the publication of the Version of Record of this article), the Accepted Manuscript is fully protected by copyright and cannot be reused or reposted elsewhere. 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