Abstract
The fabrication of flexible, stretchable and rechargeable devices with a high energy density is critical for next-generation electronics. Herein, fiber-shaped Zn–air batteries, are realized for the first time by designing aligned, cross-stacked and porous carbon nanotube sheets simultaneously that behave as a gas diffusion layer, a catalyst layer, and a current collector. The combined remarkable electronic and mechanical properties of the aligned carbon nanotube sheets endow good electrochemical properties. They display excellent discharge and charge performances at a high current density of 2?A g−1. They are also flexible and stretchable, which is particularly promising to power portable and wearable electronic devices.