主题词:Hypercoordination,Fluxionality,Buckyball, Global Minima Searching, Star, Doublhelix,Nanowheel,Superalkali And Superhalogen,Noble Gas,Catalysis,Watesplitting,Hydrogen Storage,Sandwichespart 1: Introductory Information About Experimental And Theoretical Tools In Cluster Chemistryto Cluster Chemistry2. The Essence And Application Of Global Minima Searching Code In Cluster Chemistry3. Modern Experimental Techniques To Generate And Characterize Atomic Clusterspart 2: Unusual Structural Diversity In Clusters4. Clusters With Planar Tetracoordinate Carbon5. Clusters With Planar Pentacoordinate Carbon And Beyond6. Boron Nanorotors In Cluster Chemistry7. Boron Buckyball And Reactivityin Cluster Chemistry8. Clusters With Ultrashort Bond Distance9. Molecular Stars In Cluster Chemistry10. Highly Symmetric Nanoclusters11. Zwitterionic Clusters12. Bimetallic Clusters: Effect Of Doping On Stability And Reactivity13. Inorganic Doublhelix In Cluster Chemistry14. Nanowheels In Cluster Chemistry15. Sandwiches And Inverse Sandwiches In Cluster Chemistrypart 3: Reactivity And Application Of Clusters16. Clusters With Reactivity Towards Noble Gas17. Carbon Monoxide And Dinitrogen Fixation By Clusters18. Clusters With Catalytic Property19. Superalkali And Superhalogen Property Of Clusters20. Cluster Assisted Watesplitting21. Relativistic Effects Induced Reactivity In Gold Clusters22. Hydrogen Storage Perspective Of Clusters