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期刊名称: MRS Bulletin
Volume:35    Issue:11    
ISSN:0883-7694

Advances in actinide solid-state and coordination chemistry期刊论文

作者: Burns Peter C Ikeda Y Czerwinski K
DOI:10.1557/mrs2010.713

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期刊名称: MRS Bulletin
ISSN: 0883-7694
卷期: Volume:35    Issue:11
语言: English
摘要: Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion. The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties. The U(VI) tetraoxide core has been added to this cation's repertoire of coordination possibilities. The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands. Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group.
相关主题: nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), NANOSCIENCE AND NANOTECHNOLOGY, INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY,

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